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91.
J.D. Martín-Martín J. Tritlla E. Cardellach D. Gmez-Gras 《Journal of Geochemical Exploration》2006,89(1-3):267
Fluid inclusions and clay mineralogy of the Permo-Triassic rocks from the Espina and Espadà Ranges (SE Iberian Chain, Spain) have been investigated to establish their relationship with hydrothermal fluid circulation during the Alpine Orogeny. Primary fluid inclusions in quartz-filled tension gashes in Permo-Triassic sandstones reveal maximum temperatures around 230 °C and very constant salinities of 8.5% wt. eq. NaCl. Secondary fluid inclusions found in quartz from the Santonian Ba–Cu–Hg deposits show similar compositional and thermodynamic characteristics, denoting an Alpine recrystallization. Clay mineral composition of Permo-Triassic mudrocks is characterized by pyrophyillite, indicating low-grade metamorphic conditions. Field observations and experimental data suggest that the crystallization of quartz in tension gashes, the formation of secondary fluid inclusions and the development of the metamorphism are contemporaneous and related to fluid circulation during the Alpine compression. Fluid flow took place along the Hercynian fault system that was reactivated during the Mesozoic rift stage and inverted during the Alpine deformation. 相似文献
92.
D. Parcerisa D. Gmez-Gras A. Trav J.D. Martín-Martín E. Maestro 《Journal of Geochemical Exploration》2006,89(1-3):318
Fe and Mn occur in calcite cements depending on the oxidizing–reducing conditions of cementing waters, which may change according to depositional and diagenetic environments. In red beds, Mn and Fe are available from the ferruginous matrix. Thus, it is possible to know the oxidizing–reducing conditions of fluids that precipitated calcite as a function of Mn and Fe content in calcite cement. A detailed petrological (with special attention to cathodoluminescence) and geochemical analysis of these cements is a useful tool to constrain the diagenetic evolution of red beds and the history of the basin where they deposited. 相似文献
93.
Guillermo Booth-Rea Jos Fernando Simancas Antonio Azor Jos Miguel Azan Francisco Gonzlez-Lodeiro Paulo Fonseca 《Comptes Rendus Geoscience》2006,338(16):1260-1267
Multi-equilibrium thermobarometry shows that low-grade metapelites (Cubito-Moura schists) from the Ossa–Morena Zone underwent HP–LT metamorphism from 340–370 °C at 1.0–0.9 GPa to 400–450 °C at 0.8–0.7 GPa. These HP–LT equilibriums were reached by parageneses including white K mica, chlorite and chloritoid, which define the earliest schistosity (S1) in these rocks. The main foliation in the schists is a crenulation cleavage (S2), which developed during decompression from 0.8–0.7 to 0.4–0.3 GPa at increasing temperatures from 400–450 °C to 440–465 °C. Fe3+ in chlorite decreased greatly during prograde metamorphism from molar fractions of 0.4 determined in syn-S1 chlorites down to 0.1 in syn-S2 chlorites. These new data add to previous findings of eclogites in the Moura schists indicating that a pile of allochtonous rocks situated next to the Beja-Acebuches oceanic amphibolites underwent HP–LT metamorphism during the Variscan orogeny. To cite this article: G. Booth-Rea et al., C. R. Geoscience 338 (2006). 相似文献
94.
Nicolas Pouvreau Belén Martin Miguez Bernard Simon Guy Wöppelmann 《Comptes Rendus Geoscience》2006,338(11):802-808
The work of searching, recovering and quality control of ancient sea-level measurements at Brest is presented. This work enables us to complete a study carried out by Cartwright in 1972, which showed a decrease in the tidal M2 semi-diurnal amplitude of 1% per century. After including these ancient data, as well as the last four decades of observations in the analysis, our results show an increase of the amplitude of M2 after 1960 and a decrease before 1880, suggesting a long-period oscillation rather than a steady secular trend. To cite this article: N. Pouvreau et al., C. R. Geoscience 338 (2006). 相似文献
95.
A Practical Procedure for the Measurement of Fragmentation by Blasting by Image Analysis 总被引:1,自引:0,他引:1
Summary. The operation of a digital image analysis system in a limestone quarry is described. The calibration of the system, required
in order to obtain moderately reliable fragmentation values, is done from muckpile sieving data by tuning the image analysis
software settings so that the fragmentation curve obtained matches as close as possible the sieving. The sieving data have
also been used to extend the fragment size distribution curves measured to sizes below the system’s optical resolution and
to process the results in terms of fragmented rock, discounting the material coming from a loose overburden (natural fines)
that is cast together with the fragmented rock. Automatic and manual operation modes of the image analysis are compared. The
total fragmentation of a blast is obtained from the analysis of twenty photographs; a criterion for the elimination of outlier
photographs has been adopted using a robust statistic. The limitations of the measurement system due to sampling, image processing
and fines corrections are discussed and the errors estimated whenever possible. An analysis of consistency of the results
based on the known amount of natural fines is made. Blasts with large differences in the amount of fines require a differentiated
treatment, as the fine sizes tend to be the more underestimated in the image analysis as they become more abundant; this has
been accomplished by means of a variable fines adjustment factor. Despite of the unavoidable errors and the large dispersion
always associated with large-scale rock blasting data, the system is sensitive to relative changes in fragmentation. 相似文献
96.
C. Schnitchen D. J. Charman E. Magyari M. Braun I. Grigorszky B. Tóthmérész M. Molnár Zs. Szántó 《Journal of Paleolimnology》2006,36(1):1-17
Peatlands offer the potential for high resolution records of water balance over Holocene timescales, yet this potential is
under-exploited in many areas of the world. Within Europe, peatlands are mostly confined to areas north of 55° N, but several
areas of southern and eastern Europe contain small peatlands which may be suitable for palaeoclimatic reconstruction. In this
paper we test the potential of peatlands in the Carpathian region for deriving quantified estimates of water table changes
using testate amoebae analysis. A training set for palaeohydrological reconstruction from testate amoebae assemblages was
obtained by collecting surface samples from 13 peatlands, including 9 from Hungary and 4 from Transylvania (Romania). Using
a simple measure of mean annual water tables estimated from staining of PVC tape, we found that some peatlands were heavily
influenced by runoff and groundwater, and were therefore not suitable as modern analogues of ombrotrophic climatically sensitive
sites. The relationship between the testate amoebae assemblages in the modern samples and the environmental variables was
explored using CCA. The CCA biplot showed that the most important variables are depth to water table and moisture content,
confirming that hydrology is a key control on taxon distribution. pH was a secondary gradient. A transfer function for % moisture
and depth to water table was established and applied to fossil assemblages from a sequence from Fenyves-tető, Transylvania,
Romania. The reconstructed water table shows a number of variations which have parallels with other palaeoclimatic records
from Europe and the North Atlantic prominent phases of higher water tables are associated with the periods 8000–8300 cal BP,
3000–2500 cal BP and after 600 cal BP. We suggest that these were periods of particular intensification of westerly airflow
which affected eastern Europe as well as western and central Europe. 相似文献
97.
Károly Posgay Tamás Bodoky Zoltán Hajnal Tivadar M. Tóth Tamás Fancsik Endre Hegeds Attila Cs. Kovács Ern Takács 《Geophysical Journal International》2006,167(1):187-203
The geologic origin of subhorizontal reflections, often observed in crustal seismic sections, was investigated by establishing metamorphic facies and strength of rocks in depth, and correlating these properties to seismic reflection sections from eastern Hungary. Estimation of the depths of metamorphic mineral stability zones utilized the principles developed by Fyfe et al. and known geothermal data of the area. The strength versus depth profile was derived by relating local seismic P -wave interval velocities to Meissner et al. 's activation energy. The results show that the series of subhorizontal reflections, observed in the Pannonian Basin, are a consequence of combined metamorphic and rheologic changes in depths. The synthesis of the integrated data set suggests that the retrograde alteration of the pre-Tertiary basement above the percolation threshold was made possible by the softening effect of shear zones and their water-conducting capacity. The subhorizontal reflections of highest energy, of the consolidated crust below the percolation threshold, originate in the depths of greenschist, amphibolite and granulite metamorphic mineral facies, which were formed in geothermal and pressure conditions similar to those existing today. These results imply the overprint of earlier (Variscan) metamorphic sequences of the crust by more recent retrograde metamorphic processes. 相似文献
98.
99.
Zoltán Wéber 《Geophysical Journal International》2006,165(2):607-621
100.
The Removal of Dissolved Metals by Hydroxysulphate Precipitates during Oxidation and Neutralization of Acid Mine Waters, Iberian Pyrite Belt 总被引:4,自引:0,他引:4
J. Sánchez España E. López Pamo E. Santofimia Pastor J. Reyes Andrés J. A. Martín Rubí 《Aquatic Geochemistry》2006,12(3):269-298
This study examines the removal of dissolved metals during the oxidation and neutralization of five acid mine drainage (AMD)
waters from La Zarza, Lomero, Esperanza, Corta Atalaya and Poderosa mines (Iberian Pyrite Belt, Huelva, Spain). These waters
were selected to cover the spectrum of pH (2.2–3.5) and chemical composition (e.g., 319–2,103 mg/L Fe; 2.85–33.3 g/L SO4=) of the IPB mine waters. The experiments were conducted in the laboratory to simulate the geochemical evolution previously
recognized in the field. This evolution includes two stages: (1) oxidation of dissolved Fe(II) followed by hydrolysis and
precipitation of Fe(III), and (2) progressive pH increase during mixing with fresh waters. Fe(III) precipitates at pH < 3.5
(stages 1 and 2) in the form of schwertmannite, whereas Al precipitates during stage 2 at pH 5.0 in the form of several hydroxysulphates
of variable composition (hydrobasaluminite, basaluminite, aluminite). During these stages, trace elements are totally or partially
sorbed and/or coprecipitated at different rates depending basically on pH, as well as on the activity of the SO4=
anion (which determines the speciation of metals). The general trend for the metals which are chiefly present as aqueous
free cations (Pb2+, Zn2+, Cu2+, Cd2+, Mn2+, Co2+, Ni2+) is a progressive sorption at increasing pH. On the other hand, As and V (mainly present as anionic species) are completely
scavenged during the oxidation stage at pH < 3.5. In waters with high activities (> 10−1) of the SO 4= ion, some elements like Al, Zn, Cd, Pb and U can also form anionic bisulphate complexes and be significantly sorbed at pH
< 5. The removal rates at pH 7.0 range from around 100% for As, V, Cu and U, and 60–80% for Pb, to less than 20% for Zn, Co,
Ni and Mn. These processes of metal removal represent a significant mechanism of natural attenuation in the IPB. 相似文献